Aim of the activity
To perform the electrolysis of water using carbon electrodes and identify the gases collected in the test tube at the electrodes.
Material used in the activity
- Plastic mug
- Rubber Stoppers
- Carbon electrodes
- 6 Volt battery
- Water
- Sulphuric acid
- 7.Two test tubes
- Switch
- Wires
Procedure
We will take a plastic mug and drill two holes at its bottom and fit rubber stoppers in the both holes. Now we insert carbon electrodes in these rubber stoppers.
After that we will connect the electrodes to a 6-volt battery and fill the mug with water so that both electrodes must immersed. Now we add a few drops of dilute sulphuric acid to the water
Now after this arrangement, we will take two test tubes filled with water and invert them over the two carbon electrodes and switch on the current and leave the apparatus undisturbed for some time.
Observation
We can see bubbles at the both the electrodes when current is passed through them. These bubbles indicate the presence of gases in the test tube at the electrodes.
These gases displace water downward in the test tube.
We can see the gas collected at the cathode (negative electrode) displaces more water compared to the gas collected at the anode (positive electrode).
The test tube at the cathode contains double volume of gas compared to the test tube at the anode.
After removing the both test tubes, we bring the burning candle near the test tubes and observe what happens-
- The gas collected at the anode causes the flame to burn more brightly.
- The gas collected at the cathode extinguishes the flame with a popping sound
The test tube at the cathode contains hydrogen and the test tube at the anode contains oxygen gas. Hydrogen gas has double volume
Explanation
The process of electrolysis decomposes water into hydrogen and oxygen
Following reaction takes place at electrodes
At cathode
Reduction reaction takes place at cathode
2H+ + 2e– →H2 gas
Hydrogen gas is produced at cathode.
At anode
2H2O →O2 gas + 4H+ +4e–
Oxygen gas is produced at anode.
Water contains two hydrogen atoms for each oxygen atom so the volume of hydrogen gas produced is double that of oxygen.
Conclusion
This activity shows the electrolysis (decomposition) of water into hydrogen and oxygen. Hydrogen gas is collected at the cathode and oxygen gas is collected at the anode.
Hydrogen gas has double volume that of oxygen.
Related Topics
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Activity 1.1 |
Activity 1.2 |
Activity 1.3 |
Activity 1.4 |
Activity 1.5 |
Activity 1.6 |
Activity 1.7 |
Activity 1.8 |
Activity 1.9 |
Activity 1.10 |
Activity 1.11 |